First thing you want to do is transfer all the LR. You shouldn't really transfer coral or fish before adding the LR.
You should never do it all at once or it'll get real messy.
What I would do is, if the coral's are detachable, carefully place them onto the substrate of the tank you're getting them from and take the live rock out and add it immediately into a barrel or a bucket of the water from the tank. Take all the LR home, get it in the position you want it to be in and think long and hard about it, because you don't want to move the coral around with the LR and do changes because you didn't like the aquascape, so it's crucial you get the rock into it's correct positioning. Also, check your flow, your light and see if it's adequate. Think about where you'll put the SPS's, the anemone and see if it'll be alright for a particular area where there is more/less lighting.
I'd give it two days to let the LR rest in the water column. Check every 6 hours during the 48 hour period for Ammonia, Nitrite, Nitrate. Be sure to monitor PH levels, salinity and temperature as well. Make a small log book, it'll be helpful.
Then what I would do is, grab a couple of the SPS's and bring them to your tank. Put them in using the appropriate acclimation methods and then see how they are. Ideally, you need 48 hours to see how they do, because if you find they are dying, then it shows there is a evident problem in the tank, so you never want to add all the corals at once, because you really need to find out if a couple of them are happy in the tank. During the time, continue to monitor the necessary parameters every 6 hours.
If they are fine and healthy and your parameters are in check, then you can continue the transfer of the rest of the coral's. Repeating the process before, monitor for 24-48 hours, inspect the corals, check param's and once that is done, you can add the fish. Stability is the key here and you've got to be very careful. If you try do everything at once, you may have a lot of loss in corals which is only going to be a smack in the pocket and will just dishearten you.
Best of luck, and keep us updated.