Here's some ideas I have for why you may be seeing a decrease in pH:
1) not enough surface agitation for adequate gas exchange... means CO2 is elevated, and that will have a DRASTIC effect on your pH. Fix: put a power head aimed at the surface of the water so it's rippling. Get chaeto in our system somehow so it removes CO2 directly from the water.
2) Odd decor items leaching organic acids: driftwood will leach tannic acid. got any in your tank?
3) Elevated phosphates: this will tie up some of your KH, which decreases the buffering capacity of your system.
4) Organic acids can be released by some corals as a defensive mechanism... zoanthids in particular come to mind. If this might be a concern for you, run some carbon through your system for a day or two. That'll remove most organic acids.
that's all I can think of to help... kalkwasser is a short-term solution (remember to go slow though! fast pH changes are bad news), but in the longer term, it would be good for you to examine your system and find the acid source.
good luck!