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They look good, but it isnt a good idea to add that many fish to a tank at one time, especially a new tank. You should be only adding one or two fish ever 3 or 4 weeks. Also it looks like you have added at least 9 chormis, which is as many fish as your tank should have in it total. For saltwater tanks you want to stick with 1 fish for every 10 gal, when the tank is well established you can fudge with this a bit, but you need to be careful. I wouldnt add any more fish to your tank, and if you want other fish you are going to need to remove some of the chromis first.
Ya, I would get ready to do a big water change
I usually mix for 24 hours, that way it stops dropping and it isnt so acidic.
In a brand new tank like yours 8 chromis would take up most if not all of your bioload. But they are highlander fish so you might end up with a smaller number in the end.